I have a LS Pro DUO LS-WVL/R1 with v1.64 firmware. Not sure if setup is the same as yours, but I was able to add a 2nd Drive and enable Raid 1 while retaining all my data on drive 1.
Like you, I initially setup my LS Pro Duo with 1 drive, then later added a 2nd drive. To enable Raid 1 without erasing my 1st drive, I went logged into the NAS menu. Then went to "System"===>"Storage". Under storage there's a section that says "Disks". It showed drive 1 and drive 2. I needed to Format drive 2.
After drive 2 was formatted, I then went to "System"===> "Storage"===>"Raid Array". In the "Raid Array" section, under the "Raid Mode" column, I click the link (i don't recall what it said becuse it only showed when I didn't have Raid enabled) which brought up another menu. This allowed me to setup RAID 1 and select which drive to preserve (Disk 1). After saving my settings, the NAS restarted and RAID 1 was enabled with my old data retained and both drives mirrored.
Hope this helps. Maybe someone more familiar with this NAS can better explain.